Its most probably a psu issue. One thing though, even though his mobo supports 1600 ram and above, @ stock an i3 540 will only allow a 1:10 ratio. Only K processors will allow a 1:12 ram ratio. To be able to attain 1866 ram clocks, he has to run at 187 bclk, which is a walk in the park for a 540. One thing that might have been preventing 2 sticks running both at a time is the DMI. He might have to back it down when running anything above 187bclk.
But before trying again, just get a decent cpu. Nasa huli ang pagsisisi.
@
AcidSuicide my seasonic is already sold bro.